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In this paper, we identify emoticon semantic confusion, a vulnerability where LLMs misinterpret ASCII-based emoticons to perform unintended and even destructive actions. To systematically study this phenomenon, we develop an automated data generation pipeline and construct a dataset containing 3,757 code-oriented test cases spanning 21 meta-scenarios, four programming languages, and varying contextual complexities. Our study on six LLMs reveals that emoticon semantic confusion is pervasive, with an average confusion ratio exceeding 38%. More critically, over 90% of confused responses yield 'silent failures', which are syntactically valid outputs but deviate from user intent, potentially leading to destructive security consequences. 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More critically, over 90% of confused responses yield 'silent failures', which are syntactically valid outputs but deviate from user intent, potentially leading to destructive security consequences. 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