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In this work, we focus on two critical yet underexplored aspects of the reasoning process: reasoning transitions capturing the distinct transitions between reasoning steps and answer candidates reflecting the variety of solution paths produced by the model. We collectively define these two aspects as thinking schemata. We observe a correlation between the diversity of thinking schemata and model performance, which motivates us to enhance diversity as a means to further improve reasoning potential. To this end, we propose Diverse Schemata Policy Optimization (DiScO), a framework that first endows the model with schemata awareness, then encourages diversity through reinforcement learning, and further promotes diverse reasoning at inference time. 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To this end, we propose Diverse Schemata Policy Optimization (DiScO), a framework that first endows the model with schemata awareness, then encourages diversity through reinforcement learning, and further promotes diverse reasoning at inference time. 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