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This paper proposes an evidence-grounded framework that jointly performs supply chain bottleneck prediction and faithful natural-language risk explanation by coupling a Temporal Graph Attention Network (TGAT) with a structured large language model (LLM) reasoning module. Using maritime hubs as a representative case study for global supply chain nodes, daily spatial graphs are constructed from Automatic Identification System (AIS) broadcasts, where inter-node interactions are modeled through attention-based message passing. 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